For some reason this all sounds very familiar to me. It has been a while since I worked on this, but I have had this apart more than once. I think it would help if you gave a few more details. Oh, and it does not sound like air in the line to me. (unless the catch you describe is actually the point where the slave moves and you actually are just squeezing air until then, but you should easily tell if that is the case.)
When you say 'it catches', is this a sort of 'catch' that you can push through, or does it completely stop?
Is the clutch actually disengaging? (does it work?)
did you feel this catch during the bleed process? or can you be sure it is not a linkage issue with the pedal (mechanical not involving the hydrolics).
As far as someone saying to hold in the slave piston rod, I am thinking they mean to actually have someone push back on it while the bleed screw is open, to get any air pocket out of the cylinder. I dont know if you can do this while it is attached to the clutch. If you do disconnect it from the linkage, dont step on the pedal without the screw open or you will probably blow the piston out of the bore.